The most recent b-physics results from the OPAL experiment at LEP are reviewed. A measurement of semileptonic B meson decays to narrow orbitally-excited charm mesons is presented first, followed by a study of charm production in b-hadron decays. Here, B refers to B+ and B0 mesons and their charge conjugates, and b-hadron refers to the admixture of hadrons containing a b quark produced in electron-positron annihilations at √s= mZ. PACS: 13.25.Hw Decays of bottom mesons – 13.20.He Decays of bottom mesons