Strong laser fields exert forces comparable to, or exceeding, the forces which bind atoms to molecules. We exploit this physics to achieve selectivity in the dissociation of triatomic cations, using a simple, intuitive approach. We propose a class of molecules for which a strong bond can be preferentially dissociated over a weak bond using a strong infrared pulse with very simple pulse parameters. Selectivity is demonstrated for a model system of the type ABC +.

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Journal Chemical Physics Letters
Citation
Matusek, D.R., Ivanov, M.Yu., & Wright, J.S. (1998). Selectivity in intense field dissociation. Chemical Physics Letters, 284(3-4), 247–253.