An adjoint of a regional chemical transport model is used to calculate location-specific temperature influences (climate penalties) on two policy-relevant ozone metrics: concentrations in polluted regions (>65 ppb) and short-term mortality in Canada and the U.S. Temperature influences through changes in chemical reaction rates, atmospheric moisture content, and biogenic emissions exhibit significant spatial variability. In particular, high-NO x, polluted regions are prominently distinguished by substantial climate penalties (up to 6.2 ppb/K in major urban areas) as a result of large temperature influences through increased biogenic emissions and nonnegative water vapor sensitivities. Temperature influences on ozone mortality, when integrated across the domain, result in 369 excess deaths/K in Canada and the U.S. over a summer season - an impact comparable to a 5% change in anthropogenic NOx emissions. As such, we suggest that NOx control can be also regarded as a climate change adaptation strategy with regard to ozone air quality. Key Points Ozone climate penalties in North America show great spatial variability High-NOx regions are among locations with the largest climate penalties NOx control can be seen as a climate change adaptation strategy

Additional Metadata
Keywords adjoint, climate penalty, mortality, ozone
Persistent URL dx.doi.org/10.1002/2013GL057623
Journal Geophysical Research Letters
Citation
Zhao, S. (Shunliu), Pappin, A.J. (Amanda J.), Morteza Mesbah, S. (S.), Joyce Zhang, J.Y. (J. Y.), Macdonald, N.L. (Nicole L.), & Hakami, A. (2013). Adjoint estimation of ozone climate penalties. Geophysical Research Letters, 40(20), 5559–5563. doi:10.1002/2013GL057623